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The invention provides a production method of a rubber promoter TBBS, sequentially comprising the following steps of: a. oxidation reaction: materials of M, tert-butylamine and an additive are added with water for even agitation and is then added with an oxidizing agent for oxidation, all materials are present in a weight ratio of M: tert-butylamine: water=1:1.2-4.0: 11-15; b. recovery of tert
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